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1

Hydrazide-Based Hypercoordinate Silicon Compounds

Daniel Kost, Inna Kalikhman

Journal:

Year:

2004

File:

PDF, 50 KB

2004

2

Hypercoordinate Silicon Complexes Based on Hydrazide Ligands. A Remarkably Flexible Molecular System

Kost, Daniel, Kalikhman, Inna

Journal:

Accounts of Chemical Research

Year:

2009

Language:

english

File:

PDF, 594 KB

english, 2009

3

An Unexpected, Sterically Driven, Methyl Halide Elimination in Pentacoordinate Siliconium Halide Salts: Silicon Complexes with Equatorial Nitrogen Coordination

Daniel Kost, Boris Gostevskii, Nikolaus Kocher, Dietmar Stalke, Inna Kalikhman

Journal:

Angewandte Chemie

Year:

2003

Language:

english

File:

PDF, 126 KB

english, 2003

4

An Unexpected, Sterically Driven, Methyl Halide Elimination in Pentacoordinate Siliconium Halide Salts: Silicon Complexes with Equatorial Nitrogen Coordination

Daniel Kost, Boris Gostevskii, Nikolaus Kocher, Dietmar Stalke, Inna Kalikhman

Journal:

Angewandte Chemie International Edition

Year:

2003

Language:

english

File:

PDF, 127 KB

english, 2003

5

ChemInform Abstract: Hypervalent Silicon Compounds

Daniel Kost, Inna Kalikhman

Journal:

Year:

1999

File:

PDF, 23 KB

1999

6

ChemInform Abstract: Hypercoordinate Silicon Complexes Based on Hydrazide Ligands. A Remarkably Flexible Molecular System

Daniel Kost, Inna Kalikhman

Journal:

Year:

2009

File:

PDF, 15 KB

2009

7

ChemInform Abstract: Steric Effect on the Formation, Structure, and Reactions of Pentacoordinate Siliconium Ion Salts

Inna Kalikhman, Boris Gostevskii, Akella Sivaramakrishna, Daniel Kost, Nikolaus Kocher, Dietmar Stalke

Journal:

Year:

2010

File:

PDF, 13 KB

2010

8

Diastereomeric hexacoordinate silicon complexes: preparation, structure and epimerization

Olga Girshberg, Inna Kalikhman, Dietmar Stalke, Bernhard Walfort, Daniel Kost

Journal:

Journal of Molecular Structure

Year:

2003

Language:

english

File:

PDF, 152 KB

english, 2003

9

Donor-stabilized silyl cations: Part 7: Neutral hexacoordinate and ionic pentacoordinate silicon chelates with N-isopropylideneimino-acylimidato ligands

Inna Kalikhman, Boris Gostevskii, Olga Girshberg, Akella Sivaramakrishna, Nikolaus Kocher, Dietmar Stalke, Daniel Kost

Journal:

Journal of Organometallic Chemistry

Year:

2003

Language:

english

File:

PDF, 578 KB

english, 2003

10

Competing reactions of hypercoordinate silicon dichelates

Inna Kalikhman, Boris Gostevskii, Evgenia Kertsnus, Stephan Deuerlein, Dietmar Stalke, Mark Botoshansky, Daniel Kost

Journal:

Journal of Physical Organic Chemistry

Year:

2008

Language:

english

File:

PDF, 242 KB

english, 2008

11

Low-temperature ionization of neutral hexacoordinate to ionic pentacoordinate silicon complexes. Unusual temperature, solvent and substituent effects

Daniel Kost, Inna Kalikhman, Vijeyakumar Kingston, Boris Gostevskii

Journal:

Journal of Physical Organic Chemistry

Year:

2002

Language:

english

File:

PDF, 87 KB

english, 2002

12

Experimental Charge Density Studies of Cyclotetrasilazane and Metal Complexes Containing the Di- and Tetraanion

Nikolaus Kocher, Carola Selinka, Dirk Leusser, Daniel Kost, Inna Kalikhman, Dietmar Stalke

Journal:

Zeitschrift für anorganische und allgemeine Chemie

Year:

2004

Language:

english

File:

PDF, 527 KB

english, 2004

13

Neutral Hexacoordinate Mixed Trichelate Silicon Complexes, Structure and Stereodynamics

Evgenia Kertsnus-Banchik, Einat Sela, Jörg Wagler, Inna Kalikhman, Daniel Kost

Journal:

Zeitschrift für anorganische und allgemeine Chemie

Year:

2009

Language:

english

File:

PDF, 441 KB

english, 2009

14

Hexacoordinate Silacyclobutane Dichelate Complexes: Structure, Properties, and Ligand Crossover

Yakubovich, Shiri, Gostevskii, Boris, Kalikhman, Inna, Botoshansky, Mark, Gusel’nikov, Leonid E., Pestunovich, Vadim A., Kost, Daniel

Journal:

Organometallics

Year:

2011

Language:

english

File:

PDF, 1.22 MB

english, 2011

15

Si−E (E = N, O, F) Bonding in a Hexacoordinated Silicon Complex: New Facts from Experimental and Theoretical Charge Density Studies

Kalikhman, Inna, Engels, Bernd, Stalke, Dietmar, Kocher, Nikolaus, Henn, Julian, Gostevskii, Boris, Kost, Daniel

Journal:

Journal of the American Chemical Society

Year:

2004

Language:

english

File:

PDF, 434 KB

english, 2004

16

Donor-Stabilized Silyl Cations. 11. Bis-Zwitterionic Penta- and Hexacoordinate Silicon Dichelate Complexes Derived from (ClCH2)2SiCl2 through Double Internal Displacement of Chloride1

Gostevskii, Boris, Zamstein, Noa, Korlyukov, Alexander A., Baukov, Yuri I., Botoshansky, Mark, Kaftory, Menahem, Kocher, Nikolaus, Stalke, Dietmar, Kalikhman, Inna, Kost, Daniel

Journal:

Organometallics

Year:

2006

Language:

english

File:

PDF, 185 KB

english, 2006

17

Donor-Stabilized Silyl Cations. 3. Ionic Dissociation of Hexacoordinate Silicon Complexes to Pentacoordinate Siliconium Salts Driven by Ion Solvation1

Kost, Daniel, Kingston, Vijeyakumar, Gostevskii, Boris, Ellern, Arkady, Stalke, Dietmar, Walfort, Bernhard, Kalikhman, Inna

Journal:

Organometallics

Year:

2002

Language:

english

File:

PDF, 199 KB

english, 2002

18

Crystal Structure and Unambiguous Assignment of Two Ligand Exchange Barriers in Neutral Pentacoordinate Silicon Complexes: Correlation of 29Si and 15N Chemical Shifts and Si−N Cleavage Barriers

Kalikhman, Inna, Krivonos, Sonia, Ellern, Arkady, Kost, Daniel

Journal:

Organometallics

Year:

1996

Language:

english

File:

PDF, 179 KB

english, 1996

19

Equilibrium between neutral hexacoordinate silicon complexes and ionic pentacoordinate siliconium salts through fast dissociation–recombination of the Si–Cl bond

Kingston, Vijeyakumar, Gostevskii, Boris, Kalikhman, Inna, Kost, Daniel

Journal:

Chemical Communications

Year:

2001

Language:

english

File:

PDF, 72 KB

english, 2001

20

Silicon rehybridization and molecular rearrangements in hypercoordinate silicon dichelates

Kost, Daniel, Gostevskii, Boris, Kalikhman, Inna

Journal:

Pure & Applied Chemistry

Year:

2007

Language:

english

File:

PDF, 805 KB

english, 2007

21

Neutral Hexacoordinate Silicon Complexes. Synthesis, Structure, and Stereodynamics: Evidence for Two Nondissociative Ligand-Exchange Mechanisms

Kost, Daniel, Kalikhman, Inna, Raban, Morton

Journal:

Journal of the American Chemical Society

Year:

1995

Language:

english

File:

PDF, 1.30 MB

english, 1995

22

Donor-Stabilized Silyl Cations. 10. Pentacoordinate Siliconium-Ion Salts with a Triphenylphosphinimino- N Ligand Group: Two-Bond P−N−Si Coupling as a Measure for Coordination Strength 1

Sivaramakrishna, Akella, Kalikhman, Inna, Kertsnus, Evgenia, Korlyukov, Alexander A., Kost, Daniel

Journal:

Organometallics

Year:

2006

Language:

english

File:

PDF, 183 KB

english, 2006

23

Donor-Stabilized Silyl Cations. 12. 1 Electrochemical Evidence for Ionic Dissociation of Hexacoordinate Silicon Complexes

Jouikov, Viatcheslav, Gostevskii, Boris, Kalikhman, Inna, Kost, Daniel

Journal:

Organometallics

Year:

2007

Language:

english

File:

PDF, 216 KB

english, 2007

24

New Zwitterionic Pentacoordinate Silicates with Si ONFC 2 , Si ONF 2 C, and Si O 2 N 2 C Frameworks: Synthesis, Structure, and Dynamic Stereochemistry

Kost, Daniel, Kalikhman, Inna, Krivonos, Sonia, Bertermann, Rüdiger, Burschka, Christian, Neugebauer, Ruth E., Pülm, Melanie, Willeke, Reiner, Tacke, Reinhold

Journal:

Organometallics

Year:

2000

Language:

english

File:

PDF, 257 KB

english, 2000

25

Complete Intermolecular Ligand Crossover in Hexacoordinate Silicon Dichelates. Establishment of a Ligand Priority Order

Sergani, Shlomi, Kalikhman, Inna, Yakubovich, Shiri, Kost, Daniel

Journal:

Organometallics

Year:

2007

Language:

english

File:

PDF, 84 KB

english, 2007

26

Spin Coupling through the N→Si Dative Bond in Penta- and Hexacoordinate Hydrido- and Fluorosilicon Complexes; Coupling through a Rapidly Dissociating−Recombining N→Si Bond

Kalikhman, Inna, Gostevskii, Boris, Kingston, Vijeyakumar, Krivonos, Sonia, Stalke, Dietmar, Walfort, Bernhard, Kottke, Thomas, Kocher, Nikolaus, Kost, Daniel

Journal:

Organometallics

Year:

2004

Language:

english

File:

PDF, 167 KB

english, 2004

27

Crystal Structures and Stereodynamics of Neutral Hexacoordinate Silicon Chelates: Use of an Optically Active Ligand for Assignment of an Intramolecular Ligand Exchange Process

Kost, Daniel, Kalikhman, Inna, Krivonos, Sonia, Stalke, Dietmar, Kottke, Thomas

Journal:

Journal of the American Chemical Society

Year:

1998

Language:

english

File:

PDF, 99 KB

english, 1998

28

Donor-Stabilized Silyl Cations. 9. Two Dissociation Patterns of Hexacoordinate Silicon Complexes: A Model Nucleophilic Substitution at Pentacoordinate Silicon 1

Gostevskii, Boris, Silbert, Gilad, Adear, Keren, Sivaramakrishna, Akella, Stalke, Dietmar, Deuerlein, Stephan, Kocher, Nikolaus, Voronkov, Mikhail G., Kalikhman, Inna, Kost, Daniel

Journal:

Organometallics

Year:

2005

Language:

english

File:

PDF, 205 KB

english, 2005

29

Pentacoordinate Silyl Cations Stabilized by Coordination with Oxygen Donors: Crystal Structure, Charge Distribution, and Stereodynamics

Kalikhman, Inna, Krivonos, Sonia, Lameyer, Lutz, Stalke, Dietmar, Kost, Daniel

Journal:

Organometallics

Year:

2001

Language:

english

File:

PDF, 61 KB

english, 2001

30

Tautomeric Equilibrium between Penta- and Hexacoordinate Silicon Chelates. A Chloride Bridge between Two Pentacoordinate Silicons

Kalikhman, Inna, Girshberg, Olga, Lameyer, Lutz, Stalke, Dietmar, Kost, Daniel

Journal:

Journal of the American Chemical Society

Year:

2001

Language:

english

File:

PDF, 141 KB

english, 2001

31

Irreversible Rearrangement in Hexacoordinate Silicon Complexes: From Neutral Bis(N→Si) Chelates to Mono(N→Si) Zwitterionic λ 6 -Silicates

Kalikhman, Inna, Girshberg, Olga, Lameyer, Lutz, Stalke, Dietmar, Kost, Daniel

Journal:

Organometallics

Year:

2000

Language:

english

File:

PDF, 177 KB

english, 2000

32

Reversible Neutral Dissociation of the N−Si Dative Bond in Hexacoordinate Hydrido Complexes of Silicon

Kalikhman, Inna, Kertsnus-Banchik, Evgenia, Gostevskii, Boris, Kocher, Nikolaus, Stalke, Dietmar, Kost, Daniel

Journal:

Organometallics

Year:

2009

Language:

english

File:

PDF, 128 KB

english, 2009

33

Donor-Stabilized Silyl Cations 4: N -Isopropylidene Hydrazides, Novel Bidentate Ligands for Penta- and Hexacoordinate Silicon Chelates 1

Kalikhman, Inna, Gostevskii, Boris, Girshberg, Olga, Krivonos, Sonia, Kost, Daniel

Journal:

Organometallics

Year:

2002

Language:

english

File:

PDF, 61 KB

english, 2002

34

Regioselective Intramolecular Chloride Displacement Leading to Five- or Six-Membered Chelate-Ring Closure and Pentacoordinate Silicon Complexes: A Facile Wawzonek Rearrangement †

Yakubovich, Shiri, Gostevskii, Boris, Kalikhman, Inna, Kost, Daniel

Journal:

Organometallics

Year:

2009

Language:

english

File:

PDF, 1.09 MB

english, 2009

35

Hexacoordinate Complexes of Silacyclobutane: Spontaneous Ring Opening and Rearrangement

Gostevskii, Boris, Kalikhman, Inna, Tessier, Claire A., Panzner, Matthew J., Youngs, Wiley J., Kost, Daniel

Journal:

Organometallics

Year:

2005

Language:

english

File:

PDF, 92 KB

english, 2005

36

Competitive Molecular Rearrangements in Hexacoordinate Cyano-Silicon Dichelates

Kalikhman, Inna, Gostevskii, Boris, Kertsnus, Evgenia, Botoshansky, Mark, Tessier, Claire A., Youngs, Wiley J., Deuerlein, Stephan, Stalke, Dietmar, Kost, Daniel

Journal:

Organometallics

Year:

2007

Language:

english

File:

PDF, 155 KB

english, 2007

37

Hydride Migration from Silicon to an Adjacent Unsaturated Imino Carbon: Intramolecular Hydrosilylation

Kertsnus-Banchik, Evgenia, Kalikhman, Inna, Gostevskii, Boris, Deutsch, Zvicka, Botoshansky, Mark, Kost, Daniel

Journal:

Organometallics

Year:

2008

Language:

english

File:

PDF, 293 KB

english, 2008

38

Unusual Spin−Spin Interactions across the Coordination Bond in Hexacoordinate Silicon Complexes: Crystal-Structure Coupling Relationship

Kalikhman, Inna, Krivonos, Sonia, Stalke, Dietmar, Kottke, Thomas, Kost, Daniel

Journal:

Organometallics

Year:

1997

Language:

english

File:

PDF, 109 KB

english, 1997

39

Donor-Stabilized Silyl Cations. 8. Carbon−Carbon Bond Formation through a Novel Interchelate Molecular Rearrangement in Pentacoordinate Siliconium-Ion Salts 1

Gostevskii, Boris, Pestunovich, Vadim, Kalikhman, Inna, Sivaramakrishna, Akella, Kocher, Nikolaus, Deuerlein, Stephan, Leusser, Dirk, Stalke, Dietmar, Kost, Daniel

Journal:

Organometallics

Year:

2004

Language:

english

File:

PDF, 88 KB

english, 2004

40

Donor-Stabilized Silyl Cations. 5. Comparison between Mono- and Binuclear Siliconium Chelates 1

Kalikhman, Inna, Kingston, Vijeyakumar, Gostevskii, Boris, Pestunovich, Vadim, Stalke, Dietmar, Walfort, Bernhard, Kost, Daniel

Journal:

Organometallics

Year:

2002

Language:

english

File:

PDF, 197 KB

english, 2002

41

Dinuclear Silicon Complexes of Uracil, Barbituric Acid, and 5,5-Dimethylbarbituric Acid: Hydrolytic Formation of Cyclic Oligomers(1) †

Kertsnus-Banchik, Evgenia, Gostevskii, Boris, Botoshansky, Mark, Kalikhman, Inna, Kost, Daniel

Journal:

Organometallics

Year:

2010

Language:

english

File:

PDF, 2.37 MB

english, 2010

42

Octahedral and Bicapped-Tetrahedral Silicon Configurations in the Solid State and Their Dynamic Coexistence in Solution

Kalikhman, Inna, Gostevskii, Boris, Botoshansky, Mark, Kaftory, Menahem, Tessier, Claire A., Panzner, Matthew J., Youngs, Wiley J., Kost, Daniel

Journal:

Organometallics

Year:

2006

Language:

english

File:

PDF, 186 KB

english, 2006

43

Neutral and ionic dissociation patterns in hexacoordinate silicon chelates: a model nucleophilic substitution at pentacoordinate silicon

Gostevskii, Boris, Adear, Keren, Sivaramakrishna, Akella, Silbert, Gilad, Stalke, Dietmar, Kocher, Nikolaus, Kalikhman, Inna, Kost, Daniel

Journal:

Chemical Communications

Year:

2004

Language:

english

File:

PDF, 110 KB

english, 2004

44

Stereodynamics of neutral six-coordinate silicon chelates: evidence for two non-dissociative rate processes

Kalikhman, Inna, Kost, Daniel, Raban, Morton

Journal:

Journal of the Chemical Society Chemical Communications

Year:

1995

Language:

english

File:

PDF, 280 KB

english, 1995

45

Facile central-element exchange in neutral hexacoordinate germanium and silicon complexes; synthesis and characterization of germanium complexes

Yakubovich, Shiri, Kalikhman, Inna, Kost, Daniel

Journal:

Dalton Transactions

Year:

2010

Language:

english

File:

PDF, 237 KB

english, 2010

46

Neutral Hexacoordinate Silicon Tris-Chelates: Structure and Stereodynamics †

Kalikhman, Inna, Kingston, Vijeyakumar, Girshberg, Olga, Kost, Daniel

Journal:

Organometallics

Year:

2001

Language:

english

File:

PDF, 151 KB

english, 2001